Question regarding emulation save states and RNG manipulation for shiny starter.

Waiting for my new switch 2 to arrive and I want to try some rng manipulation for the first time on my emulator.

From what I can tell rng manipulation requires knowing your sid along with your tid, and apparently using ACE commands there is a way to see what your sid is. Instead of not saving up to and including ACE commands, can I use save states instead of the standard save file and still be able to load the original standard save once I obtain my sid, or will save states introduce unknown values/variables that will mess up the entire process?