Can I play the entire Metal Gear series on PS5 after Master Collection Vol. 2?

When Metal Gear Solid: Master Collection Vol. 2 releases on August 27th, will that mean we finally have all the games needed to play the series in release order?

- I've never played the series, but I'd like to get into it.

- I have a PS5 and a Legion Go. I already have the classic games on my Legion Go through emulation.

- On PS5, I know I'll be able to play Metal Gear Solid V: Ground Zeroes, The Phantom Pain, and Metal Gear Solid Delta: Snake Eater.

Given that, what would you suggest? Will I be able to play the entire series on PS5 after August 27th?