-Ghostface-

Always wanted to do this and now that I have some time in my 30s, good way to interact

Ask away 🏴‍☠️

Been extremely busy this year, haven’t kept up with players outside of the leafs this season.

All I know is the leafs have been linked with Tanev(shipped off to Dallas) and saros (yeah not happening)

Which top 4 RD are we looking at?? (Hearing a lot about this Sean walker dude- he any good? )

Hey people, hope you're all doing well
I recently have been introduced to this medium and got to say I love it.

Husband and I have watched: Start-Up (disliked the ending, everything else was perfect), Goblin and My First First Love (MFFL)
The reason for this post is because of MFFL, it is the perfect show, my husband hasn't stopped talking about how incredible the story, character and setting (real world), and especially the fact that the main couple actually ended up together.
We wanted to continue that journey, looking for a show that is about the struggles of life, friends, comedy and where the right couple end up together. Oh and in the real world setting, don't want to delve int

Describe the preparation of 500 mL of a 0.100 M propanoate buffer that has a pH of 4.90. Assume you have solid sodium propanoate (NaC3H5O2) and 0.250 M propanoic acid (HC3H5O2).

answer: 2.42 g of NaC3H5O2 and 98.8 mL of 0.250 M HC3H5O2 diluted to 500 mL

​

Despite having the answer, I still am incapable of understanding how to go about this (Professor, textbook, and online videos did not help)

Describe the preparation of 500 mL of a 0.100 M propanoate buffer that has a pH of 4.90. Assume you have solid sodium propanoate (NaC3H5O2) and 0.250 M propanoic acid (HC3H5O2).

answer: 2.42 g of NaC3H5O2 and 98.8 mL of 0.250 M HC3H5O2 diluted to 500 mL

​

Despite having the answer, I still am incapable of understanding how to go about this

Been car shopping after my RDX broke down and I have two options in front of me

2016 Mercedes CLA Sports package

• driven 150000 km
• $3000 carfax claim
• final price after taxes $24,500 (cdn)
• I can find a cleaner title with fewer km but I’m looking around $27k

2014 Lexus IS 250 F Sport

• driven 165000 km
• $3000 carfax claim
• final price after taxes $22,500

I’d rather not go over $25k but it’s about reliability, I can look at other options and cars but I’m in love with both of them, though the Lexus has been a dream car. Unfortunately, I’m not a car head, I don’t know much about them. So I’m trusting you strangers:

• which one costs less in terms of maintenance?
• which one will las

Been car shopping after my RDX broke down and I have two options in front of me

2016 Mercedes CLA Sports package

• driven 150000 km
• $3000 carfax claim
• final price after taxes $24,500 (cdn)
• I can find a cleaner title with fewer km but I’m looking around $27k

2014 Lexus IS 250 F Sport

• driven 165000 km
• $3000 carfax claim
• final price after taxes $22,500

I’d rather not go over $25k but it’s about reliability, I can look at other options and cars but I’m in love with both of them, though the Lexus has been a dream car. Unfortunately, I’m not a car head, I don’t know much about them. So I’m trusting you strangers:

• which one costs less in terms of maintenance?
• which one will las

Been car shopping after my RDX broke down and I have two options in front of me

2016 Mercedes CLA Sports package

• driven 150000 km
• $3000 carfax claim
• final price after taxes $24,500 (cdn)
• I can find a cleaner title with fewer km but I’m looking around $27k

2014 Lexus IS 250 F Sport

• driven 165000 km
• $3000 carfax claim
• final price after taxes $22,500

I’d rather not go over $25k but it’s about reliability, I can look at other options and cars but I’m in love with both of them, though the Lexus has been a dream car. Unfortunately, I’m not a car head, I don’t know much about them. So I’m trusting you strangers:

• which one costs less in terms of maintenance?
• which one will las

All my friends and family said to stay away from audi's. My wife and I fell in love with the Audi Q3, but unfortunately, due to circumstances, our budget allows for either a :

- 2015 Audi Q3, driven 150 000 km, TSFI engine (which apparently is bad)

- 2014 Audi Q5, driven 140 000km, TSFI engine

I don't know much about the mechanical parts when it comes to cars, but would you experts say that it's worth getting one of these 2? It will be an everyday-use car, but I am worried about constantly being in the shop because "audi's" need a lot of work on them apparently and it's expensive.