I can't find anyone else with this problem so this is my last attempt to fix it.
I've been doing 5/6 star raids for the past 2 days straight with NO herba mystica drops. Yes, I know it's rare. Yes, I have been doing the ones with increased drop rates (ie dondozo, blissey, etc).
In the past, I have never had this problem, but after I union circled with a couple of friends this issue showed up. The last time I got an herba mystica drop was in that same union circle, one sweet herba mystica. However, it has completely disappeared from my inventory, along with 2 herba mystica I was like 99% sure I also had. It's like the items have been deleted from my game entirely.
So.. any thoughts? Any
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